全文获取类型
收费全文 | 427314篇 |
免费 | 5545篇 |
国内免费 | 1217篇 |
专业分类
化学 | 227667篇 |
晶体学 | 5206篇 |
力学 | 18636篇 |
综合类 | 13篇 |
数学 | 49635篇 |
物理学 | 132919篇 |
出版年
2021年 | 3502篇 |
2020年 | 4184篇 |
2019年 | 4517篇 |
2018年 | 5853篇 |
2017年 | 5743篇 |
2016年 | 8831篇 |
2015年 | 5561篇 |
2014年 | 8542篇 |
2013年 | 20183篇 |
2012年 | 15647篇 |
2011年 | 19261篇 |
2010年 | 13497篇 |
2009年 | 13350篇 |
2008年 | 17647篇 |
2007年 | 17541篇 |
2006年 | 16252篇 |
2005年 | 14550篇 |
2004年 | 13436篇 |
2003年 | 11644篇 |
2002年 | 10711篇 |
2001年 | 12971篇 |
2000年 | 9473篇 |
1999年 | 7303篇 |
1998年 | 5988篇 |
1997年 | 5884篇 |
1996年 | 5606篇 |
1995年 | 5312篇 |
1994年 | 5278篇 |
1993年 | 5068篇 |
1992年 | 5697篇 |
1991年 | 5790篇 |
1990年 | 5551篇 |
1989年 | 5354篇 |
1988年 | 5376篇 |
1987年 | 5289篇 |
1986年 | 4973篇 |
1985年 | 6475篇 |
1984年 | 6607篇 |
1983年 | 5226篇 |
1982年 | 5320篇 |
1981年 | 5303篇 |
1980年 | 4873篇 |
1979年 | 5303篇 |
1978年 | 5438篇 |
1977年 | 5346篇 |
1976年 | 5294篇 |
1975年 | 4877篇 |
1974年 | 4846篇 |
1973年 | 4848篇 |
1972年 | 3432篇 |
排序方式: 共有10000条查询结果,搜索用时 140 毫秒
91.
Umie F.M. Haziz Rosenani A. Haque Shun-Ze Zhan Hassan H. Abdallah Mohd R. Razali 《应用有机金属化学》2020,34(10):e5818
The synthesis and characterizations for a series of dinuclear gold (I)-di-NHC complexes, 1–8 through the trans-metalation method of their respective silver (I)-di-NHC complexes, i–viii are reported (where NHC = N-heterocyclic carbene). The successful complexation of a series of unusual non-symmetrical and symmetrical di-NHC ligands, 3,3'-(ethane-1,2-diyl)-1-alkylbenzimidazolium-1'-butylbenzimidazolium (with alkyl = methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, benzyl) with the gold (I) ions are suggested by elemental analysis, Fourier transform-infrared, 1H- and 13C-NMR data. The 13C-NMR spectra of 1–8 show a singlet sharp peak in the range of 190.00–192.00 ppm, indicating the presence of a carbene carbon that bonded to the gold (I) ion. From single crystal X-ray diffraction data, the structure of complex 6 with the formula of [di-NHC-Au (I)]2·2PF6 is obtained [where NHC = 3,3'-(ethane-1,2-diyl)-1-hexylbenzimidazolium-1'-butylbenzimidazolium]. The photophysical study in solid state of 6 displays an intense photoluminescence with a strong emission maxima, λem = 480 nm, upon excitation at 340 nm at room temperature. Interestingly, the emission maximum at 77 K shows a structural character with a strong peak at 410 nm, a medium at 433 nm and a weak at 387 nm, accompanied by a tail band to about 500 nm. 相似文献
92.
93.
Ein elektronenreiches cyclisches (Alkyl)(amino)carben auf Au(111)-, Ag(111)- und Cu(111)-Oberflächen
Anne Bakker Dr. Matthias Freitag Elena Kolodzeiski Peter Bellotti Dr. Alexander Timmer Dr. Jindong Ren Bertram Schulze Lammers Daniel Moock Prof. Dr. Herbert W. Roesky Dr. Harry Mönig Dr. Saeed Amirjalayer Prof. Dr. Harald Fuchs Prof. Dr. Frank Glorius 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(32):13745-13749
94.
Dr. Silvia Castro-Fernández Carlos M. Cruz Dr. Inês F. A. Mariz Dr. Irene R. Márquez Vicente G. Jiménez Lucía Palomino-Ruiz Prof. Juan M. Cuerva Dr. Ermelinda Maçôas Dr. Araceli G. Campaña 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(18):7205-7211
A new family of distorted ribbon-shaped nanographenes was designed, synthesized, and their optical and electrochemical properties were evaluated, pointing out an unprecedented correlation between their structural characteristics and the two-photon absorption (TPA) responses and electrochemical band gaps. Three nanographene ribbons have been prepared: a seven-membered-ring-containing nanographene presenting a tropone moiety at the edge, its full-carbon analogue, and a purely hexagonal one. We have found that the TPA cross-sections and the electrochemical band gaps of the seven-membered-ring-containing compounds are higher and lower, respectively, than those of the fully hexagonal polycyclic aromatic hydrocarbon (PAH). Interestingly, the inclusion of additional curvature has a positive effect in terms of non-linear optical properties of those ribbons. 相似文献
95.
96.
97.
M. S. Fedoseev V. Yu. Gusev L. F. Derzhavinskaya V. E. Antipin R. V. Tsvetkov 《Polymer Science Series D》2018,11(1):39-46
The interaction of UP-643 epoxy-novolac resin with isomethyltetrahydrophthalic anhydride in the presence of the catalysts (azo-compounds of different structure) is studied. Latency of the catalysts is found. The possibility is shown of creating epoxy binders with a long lifetime (10–40 days) at room temperatures, cured at increased temperature up to heat-resistant polymers. 相似文献
98.
99.
100.
K. E. Prikhodko M. M. Dementyeva B. A. Gurovich D. A. Komarov L. V. Kutuzov 《Crystallography Reports》2018,63(2):241-244
The change in the free-electron density in ultrathin (5 nm) superconducting NbN films in the initial state and after irradiation by O+ ions to doses of (0.1–0.9) × 1017 cm–2 has been studied by electron energy-loss spectroscopy (EELS). The analysis has been performed on cross section samples prepared by the focused ion beam method, using plasmon oscillations with energies up to 50 eV. The radiation-induced replacement of nitrogen atoms with oxygen atoms in niobium nitride is found to change the electrical properties of the material, which leads to a decrease in the free-electron density with an increase in the irradiation dose. 相似文献